No it's not headshot as in someone getting shot in the head
Some character designs from Pathfinder #7

Gaedrin - This is a lanky, withered, wrinkled old crime boss. He should look like he does in the reference, but even meaner, snarling or scowling at the viewer.

Cabbage Head - This is a fleshy-headed, deformed, half ogre. He’s called Cabbage Head. We’ll leave it up to you as to why.

Grau - This is a hardworking, forty-year-old man. He would probably be handsome, but he hasn’t shaved or bathed for more than a week. He looks depressed, but his features are respectable. This guy is the local hero who’s lost his way and needs to be boosted back up.

Zellara -This picture is of a beautiful, middle-aged, gypsy woman. She has her long curly hair held back in a colorful bandana. She’s probably nearing 40 and is very attractive. She looks like she has some sly idea or knows something the viewer doesn’t.